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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 1: Synthesis, Structure, Stereochemistry and Reactivity of Organophosphorus Compounds

Synthesis and Properties of Phosphorylated and Silylated α-Mercaptocarbonyl Compounds

Michael A. Pudovik A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
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Alexander R. Burilov A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
,
Irina L. Nikolaeva A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
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Yana A. Drozdova A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
,
Dmitriy V. Cherepashkin A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
,
Alexei A. Barulin A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
&
Arkadiy N. Pudovik A.E. ArbuzovInstitute of Organic and Physical Chemistry Kazan Branch Academy of Sciences, Arbusov Str., 8, Kazan, 420083, USSR
 show all
Pages 219-222 | Published online: 04 Oct 2006
 
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Abstract

Phosphorylation and silylation of α -mercaptooarbonyl compounds have been investigated. A novel type of 1.4 S-O migration trimethylsilyl and P(III) groups has been discovered. The thiophosphite-thiophosphonate rearrangement when exposed to oxygen as well as heterocyclization with the formation of 1,3,2-oxathiaphospholenes and 1,3,2-oxathiasilalenes were also found. Some regularities of these processes and the properties of heterocycles synthesized have also been brought out.

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