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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 2: Chemistry of Phosphorus Compounds in Particular Coordination Bonding

Iminophosphanes and Diphosphenes - Recent Developments

E. Niecke Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
,
O. Altmeyer Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
,
D. Barion Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
,
R. Detsch Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
,
C. Gåtner Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
,
J. Hein Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
,
M. Nieger Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
&
F. Reichert Anorganisch-Chemísches Institut der Universität Bonn, Gerhard-Domagk-Str.1, 5300, Bonn 1, FRG
 show all
Pages 321-324 | Published online: 04 Oct 2006
 
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Abstract

Novel iminophosphane derivatives are synthesized by nucleophilic displacement from Cl-P=NMes*. Structures, spectroscopic data, and novel chemical reactions of these compounds are discussed. Furthermore, synthesis of stable cis- and trans isomers of a diphos phene, as well as their mutual interconversion, is reported.

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