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Section 3: Chemistry of Phosphorus Coordination Compounds

Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μ-S2 Groups Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3

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Pages 425-428 | Published online: 04 Oct 2006
 

Abstract

A family of dirhodium complexes containing bridging chalcogen compounds has been synthesized and fully characterized by X-ray methods and NMR spectroscopy. The reactivity of the disulphido complex [(triphos)Rh(μ-S)2Rh(triphos)][BPh4]2 has been studied in detail.

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