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Section 3: Chemistry of Phosphorus Coordination Compounds

Copper(I) Complexes with Electron Deficient μ3-PRR′ Bridging - a Novel Coordination Mode of Secondary Phosphido Groups in Transition Metal Chemistry

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Pages 449-452 | Published online: 04 Oct 2006
 

Abstract

Copper(1) phosphido complexes containing electron deficient μ3-PRR′ bridges are formed by P-Si cleavage reactions in silylphoshines with CuCl or by depolymerization of polymeric [Cu(PPh2)]n with PMe3 or PMe3/CuCl.

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