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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 3: Chemistry of Phosphorus Coordination Compounds

Decisive Influence of Phosphorus Ligands on O2 Oxidations of Alkenes in the Presence of the Iron Nitrato/Iron Nitrosyl Couple

Michèle Postel Laboratoire de Chimie Moléculaire Unité Associée au C.N.R.S. n 426, Université de Nice, 06034, Nice, France
,
Félix Tomi Laboratoire de Chimie Moléculaire Unité Associée au C.N.R.S. n 426, Université de Nice, 06034, Nice, France
,
Henri Li Kam Wah Laboratoire de Chimie Moléculaire Unité Associée au C.N.R.S. n 426, Université de Nice, 06034, Nice, France
,
Laurence Mordenti Laboratoire de Chimie Moléculaire Unité Associée au C.N.R.S. n 426, Université de Nice, 06034, Nice, France
&
Patricia Guillaume Laboratoire de Chimie Moléculaire Unité Associée au C.N.R.S. n 426, Université de Nice, 06034, Nice, France
Pages 453-457 | Published online: 04 Oct 2006
 
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Abstract

Fe(NO)2XL and Fe(NO)X2L nitrosyl iron complexes, X = Cl, I, and L = HMPA, dppe, PPh3, activate molecular O2 to yield nitrato complexes. The phosphorous ligand is decisive for the oxidative power of these nitrates: with HMPA or dppe, oxygen transfer occurs only to phosphines. On going from HMPA to PPh3 the single nitrato complex obtained, Fe(NO)2X(OPPh3)2 selectively epoxidizes cyclohexene, and this is the first example of oxygen transfer from a nitrato ligand to an olefin.

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