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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 3: Chemistry of Phosphorus Coordination Compounds

Reactions of a Cyclenphosphoranide Platinum (II) Complex and the Role of Highly Nucleophilic Substituents at the Axial Positions of a Trigonal Bipyramid

Dilip V. Khasnis Department of Chemistry, Southern Methodist University, Dallas, Texas, 75275, U.S.A.
,
Michael Lattman Department of Chemistry, Southern Methodist University, Dallas, Texas, 75275, U.S.A.
&
Upali Siriwardane Department of Chemistry, Southern Methodist University, Dallas, Texas, 75275, U.S.A.
Pages 459-462 | Published online: 04 Oct 2006
 
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Abstract

(η2-cyclenP)Pt(Cl)PPh3 1 exhibits a large variety of selective reactions due to the platinum metal and cyclenphosphoranide ligand, cyclenP. Moreover, the cyclenP ligand is capable of altering many of the usual reactions and/or mechanisms at square planar platinum (II) complexes.

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