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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 61, 1991 - Issue 1-2
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Original Articles

ORGANIC PHOSPHORUS COMPOUNDS 96.1 RESOLUTION OF 1-AMINO-2-(4-FLUOROPHENYL)ETHYLPHOSPHONIC ACID AS WELL AS SOME DI- AND TRIPEPTIDES

Ludwig Maier CIBA-GEIGY AG, Division Agro, 4002, Basel, Switzerland
&
H. Spörri CIBA-GEIGY AG, Division Agro, 4002, Basel, Switzerland
Pages 69-75 | Received 04 Jan 1991, Published online: 23 Sep 2006
 
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Abstract

Resolution of racemic 1-amino-2-(4-fluorophenyl)ethylphosphonic acid with dibenzoyltartrate is easily accomplished. In the inhibition of PAL 2b(-) is about five times as active as 2a(+). The synthesis of the dipeptides 5a and 5b, and of the tripeptides 8a and 8b is described and comments are made on their biological activity.

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