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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 60, 1991 - Issue 3-4
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Original Articles

THE REDUCTION OF CYCLIC DISULPHIDES WITH TRIARYLPHOSPHINES IN AQUEOUS ORGANIC SOLVENTS

A. Salim Department of Chemistry and Biological Chemistry, University of Essex, Colchester, U. K.; College of Science, King saud University, P.O. Box 2456, Riyadh, Saudi Arabia
&
J. G. Tillett Department of Chemistry and Biological Chemistry, University of Essex, Colchester, U. K.
Pages 215-222 | Received 10 Oct 1990, Accepted 15 Nov 1990, Published online: 23 Sep 2006
 
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Abstract

The kinetics of the reduction of cyclic disulphides with triphenylphosphine have been studied in aqueous ethanol at various temperatures. Solvent effects on the reaction of 4-phenyl-1,2-dithiolane with tris-(4chlorophenyl) phosphine in a number of aqueous organic solvents have been analysed in terms of the Kirkwood, Y and EN T functions.

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