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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 61, 1991 - Issue 3-4
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Original Articles

INTERACTION OF DISULFIDES AND SULFENYLCHLORIDES WITH C[sbnd]N,N-DIALKYLAMINOSUBSTITUTED PHOSPHAALKENES

A. S. Ionkin A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Centre of the USSR Academy of Sciences, 8, A. E. Arbuzov Street, Kazan, 420083, USSR
,
N. V. Nikolaeva A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Centre of the USSR Academy of Sciences, 8, A. E. Arbuzov Street, Kazan, 420083, USSR
,
V. M. Nekhoroshkov A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Centre of the USSR Academy of Sciences, 8, A. E. Arbuzov Street, Kazan, 420083, USSR
,
Yu. Ya. Efremov A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Centre of the USSR Academy of Sciences, 8, A. E. Arbuzov Street, Kazan, 420083, USSR
&
B. A. Arbuzov A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Centre of the USSR Academy of Sciences, 8, A. E. Arbuzov Street, Kazan, 420083, USSR
Pages 361-365 | Received 03 Oct 1990, Accepted 14 Jan 1991, Published online: 23 Sep 2006
 
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Abstract

Interaction of dialkyl disulfides with C[sbnd]N,N-dimethylaminomethylene-P-phenylphosphine 1a results in the complete cleavage of the P[dbnd]C double bond and formation of S,S-dialkylphenyldithiophosphonites. Ethyl sulfenylchlorides undergoes dehydrochlorination by 1a, while phenyl sulfenylchloride cleaves the P[dbnd]C bond in C[sbnd]N,N-dialkylaminosubstituted phosphaalkenes with the predominant formation of either PhP(SPh)2 6 or PhP(SPh)CI 7 depending on the phosphaalkene used and reaction conditions.

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