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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 56, 1991 - Issue 1-4
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Original Articles

COMMUNICATION. OBSERVATIONS ON THE 121-Sb MÖSSBAUER PARAMETERS OF ANTIMONY (III) COMPOUNDS FEATURING A PYRAMIDAL SbS3 SKELETAL UNIT

G. Alonzo Dipartimento di Chimica Inorganica, via Archirafi 26, 1-90123, Palermo, Italy
,
M. Consiglio Dipartimento di Chimica Inorganica, via Archirafi 26, 1-90123, Palermo, Italy
,
F. Maggio Dipartimento di Chimica Inorganica, via Archirafi 26, 1-90123, Palermo, Italy
&
N. Bertazzi Dipartimento di Chimica e Tecnologie Inorganiche e Metallorganiche, via Ospedale 72, 1-09124, Cagliari, Italy
Pages 287-289 | Received 11 Apr 1990, Accepted 15 Jun 1990, Published online: 23 Sep 2006
 
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Abstract

A linear correlation between the chemical isomer shift and the quadrupole coupling constant for a number of antimony tris-thiolates has been evidenced. This behaviour can be rationalized on considering a modulation of the s/p character of the lone pair of electrons from the influence of secondary bonds.

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