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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 55, 1991 - Issue 1-4
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Original Articles

STUDIES ON ORGANOPHOSPHORUS COMPOUNDS XLV STRUCTURAL EFFECTS OF ESTER ALKYL GROUP OF DIALKYL ALLYLPHOSPHONATE CARBANION ON THE REGIOSELECTIVITY OF ELECTROPHILIC ADDITION

Chengye Yuan Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling, Lu, Shanghai, 200032, China
,
Jiachang Yao Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling, Lu, Shanghai, 200032, China
&
Shusen Li Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling, Lu, Shanghai, 200032, China
Pages 125-131 | Received 18 Apr 1990, Accepted 09 May 1990, Published online: 04 Oct 2006
 
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Abstract

The steric effect of the ester alkyl group of dialkyl allylphosphonate carbanion on the regioselectivity of the reaction with benzaldehyde was investigated. The steric contribution was evaluated by substituent parameter and molecular mechanics calculation.

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