STUDIES ON ORGANOPHOSPHORUS COMPOUNDS XL VIII STRUCTURAL EFFECT ON THE INDUCED ASYMMETRIC ADDITION OF DIALKYL PHOSPHITE TO CHIRAL ALDIMINE DERIVATIVES

Chengye Yuan Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling, Lu, Shanghai, 200032, China

Shuhua Cui Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling, Lu, Shanghai, 200032, China

Abstract

For the evaluation of the predominating factors controlling the stereochemical process of the addition of dialkylphosphite to a chiral Schiffs base resulting from condensation of substituted benzaldehyde and 1-phenylethylamine, various structural effect of the substrates and phosphorus reagents were investigated. The influence of catalyst and solvent is discussed on the basis of the conformational requirements of the complex formed.

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STUDIES ON ORGANOPHOSPHORUS COMPOUNDS XL VIII STRUCTURAL EFFECT ON THE INDUCED ASYMMETRIC ADDITION OF DIALKYL PHOSPHITE TO CHIRAL ALDIMINE DERIVATIVES

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STUDIES ON ORGANOPHOSPHORUS COMPOUNDS XL VIII STRUCTURAL EFFECT ON THE INDUCED ASYMMETRIC ADDITION OF DIALKYL PHOSPHITE TO CHIRAL ALDIMINE DERIVATIVES

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