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The reaction of cyclodiarsazanes, [(R)NAsCl]2 (R [dbnd] tert. butyl, 1,1,3,3-tetramethylbutyl, phenyl, 1-adamantyl) with the salt K2SN2 in hexane suspension leads to cage compounds in which two arsenic atoms are triply bridged by an organylimido and two sulfur diimide units.
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