α-(METHYLTHIO) BENZYL SULFONES AS SYNTHETIC INTERMEDIATES. PART V. SYNTHESES OF SOME o- AND m-SUBSTITUTED 1-DEUTERIOBENZALDEHYDES

B. Wladislaw Instituto de Química, Universidade de Säo Paulo, C.P. 20.780, CEP 01.498-Säo, Paulo, S.P., Brazil

L. Marzorati Instituto de Química, Universidade de Säo Paulo, C.P. 20.780, CEP 01.498-Säo, Paulo, S.P., Brazil

G. Ebeling Instituto de Química, Universidade de Säo Paulo, C.P. 20.780, CEP 01.498-Säo, Paulo, S.P., Brazil

Abstract

o- and m-Substituted α-methylthiobenzyl sulfones incorporate deuterium when treated with a base and deuterium oxide. The resulting deuterated sulfones, by thermal decomposition, afford o- and m-substituted 1-deuteriobenzaldehydes in good yields and high isotopic purity.

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α-(METHYLTHIO) BENZYL SULFONES AS SYNTHETIC INTERMEDIATES. PART V. SYNTHESES OF SOME o- AND m-SUBSTITUTED 1-DEUTERIOBENZALDEHYDES

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α-(METHYLTHIO) BENZYL SULFONES AS SYNTHETIC INTERMEDIATES. PART V. SYNTHESES OF SOME o- AND m-SUBSTITUTED 1-DEUTERIOBENZALDEHYDES

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