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Original Articles

STUDY ON THE REACTION OF HALOFORM WITH HEXAALKYL PHOSPHOROUS TRIAMIDES

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Pages 153-158 | Received 06 Nov 1991, Accepted 25 Feb 1992, Published online: 26 May 2009
 

Abstract

This paper reports the reactions of hexaalkyl phosphorous triamides (HEPTA) with chloroform, bromoform or iodoform. By the FAB-MS, 31P-NMR, and 13C-NMR study the structures of the products have been determined and a possible reaction mechanism has been proposed. Furthermore, the order of reactivity has been established to be: CHI3 > CHBr3 > CHCl3.

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