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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 65, 1992 - Issue 1-4
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Original Articles

Preparation and Structural Characterization of 1-Phenyl-1-(Dicyclohexylamino)Cyclo-1-Phospha-3, 5-Dithia-2, 4, 6-Triazene; a Phosphathiazene With Different Substituents on Phosphorus

T. Mohan Department of Chemistry, IIT, Madras, 600 036, India
,
C. J. Thomas Department of Chemistry, IIT, Madras, 600 036, India
,
M. N. Sudheendra Rao Department of Chemistry, IIT, Madras, 600 036, India
,
G. Aravamudan Department of Chemistry, IIT, Madras, 600 036, India
,
A. Meetsma Laboratory of Polymer Chemistry, University of Groningen, Nijenborgh 16, 9747 AG, Groningen, The Netherlands
&
J. C. van de Grampel Laboratory of Polymer Chemistry, University of Groningen, Nijenborgh 16, 9747 AG, Groningen, The Netherlands
Pages 79-81 | Published online: 06 Dec 2006
 
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Abstract

The reaction of S4N4 with dicyclohexylaminophenyl-(2-aminopyridyl)phosphine in MeCN at room temperature leads to the formation of the novel compound Ph(cycloHex2 N)PS2 N3. An X-Ray structure determination confirms that this, compound consists of a six-membered PSN-ring with two different substituents at phosphorus.

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Related Research Data

Aminophosphines: their chemistry and role as ligands and synthons
Source: Wiley

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