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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 84, 1993 - Issue 1-4
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Original Articles

PHOSPHONIC SYSTEMS. PART 13. ALKYLATION OF DIETHYL CYCLOHEXENYLPHOSPHONATES

J. P. Gerber Department of Chemistry, Vista University, Private Bag X1311, Silverton, 0127, South Africa
&
T. A. Modro Centre for Heteroatom Chemistry, Department of Chemistry, University of Pretoria, Pretoria, 0002, South Africa
Pages 107-113 | Received 26 Aug 1993, Published online: 23 Sep 2006
 
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Abstract

Alkylation of cyclohexenylphosphonates was found to proceed under very mild conditions. The reaction usually occurred in a regioselective fashion with α-addition predominating. Steric effects were significant and had a bearing on the regioselectivity of the reaction.

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