REACTIVITY OF PHOSPHONIC KETENE DITHIOACETALS TOWARDS NUCLEOPHILES

Didier Villemin Laboratoire de Chimie des Composés Thio-Organiques, Ecole Nationale Supérieure d'Ingénieurs de Caen, I.S.M.R.A., U.R.A. 480 CNRS, 6 boulevard du Maréchal Juin, 14050, Caen Cedex, France

Frédéric Thibault-Starzyk Laboratoire de Chimie des Composés Thio-Organiques, Ecole Nationale Supérieure d'Ingénieurs de Caen, I.S.M.R.A., U.R.A. 480 CNRS, 6 boulevard du Maréchal Juin, 14050, Caen Cedex, France

Abstract

The reaction of phosphonic ketene dithioacetals with two types of nucleophiles is described: alkoxides and Grignard reagents in the presence of transition metal catalysts.

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REACTIVITY OF PHOSPHONIC KETENE DITHIOACETALS TOWARDS NUCLEOPHILES

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REACTIVITY OF PHOSPHONIC KETENE DITHIOACETALS TOWARDS NUCLEOPHILES

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