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COMMUNICATION

QUANTUM-CHEMICAL STUDY ON FORMATION OF THIONITROSO COMPOUNDS FROM N-CHLORO- SULFENYL-N-TRIMETHYLSILYL AMINES

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Pages 255-258 | Received 15 Dec 1992, Accepted 08 Mar 1993, Published online: 23 Sep 2006
 

Abstract

The MNDO quantum-chemical calculations revealed that the N-chlorosulfenyl-N-trimethylsilyl amine decomposition scheme may be described as the S‒Cl bond weakening and the subsequent trimethylsilyl group transfer to the chlorine atom, with the activation barrier of 260-294 W/mol.

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