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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 74, 1993 - Issue 1-4
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Original Articles

Fluoride Ion Promoted Reactivity of Thiocarbonyl Containing Molecules with Silyl Derivatives: A Novel Access to Allyl Sulfides

Alessandro Degl'innocenti Centro CNR Composti Eterociclici, Via Gino Capponi, 9 - 50121, Firenze, (Italy)
,
Bianca Bonini Dipartimento di Chimica Organica “A. Mangini”, Viale Risorgimento, 4 - 40100, Bologna, (Italy)
,
Germana Mazzanti Dipartimento di Chimica Organica “A. Mangini”, Viale Risorgimento, 4 - 40100, Bologna, (Italy)
,
Antonella Capperucci Dipartimento di Chimica Organica “U. Schiff”, Via Gino Capponi, 9 - 50121, Firenze, (Italy)
,
M. Cristiana Ferrara Dipartimento di Chimica Organica “U. Schiff”, Via Gino Capponi, 9 - 50121, Firenze, (Italy)
,
Alfredo Ricci Centro CNR Composti Eterociclici, Via Gino Capponi, 9 - 50121, Firenze, (Italy); Dipartimento di Chimica Organica “A. Mangini”, Viale Risorgimento, 4 - 40100, Bologna, (Italy)
&
Paolo Zani Dipartimento di Chimica Organica “A. Mangini”, Viale Risorgimento, 4 - 40100, Bologna, (Italy)
 show all
Pages 365-366 | Published online: 23 Sep 2006
 
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Abstract

Fluoride ion induced reaction of allyl- and benzyl-silanes with thiocarbonyls leads, contrary to the corresponding lithium or Grignard reagents, to products of S-functionalization.

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