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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 74, 1993 - Issue 1-4
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Original Articles

Molecular Designing of Chiral α-Alkoxycarbonylthioaldehydes and their Asymmetric Diels-Alder Reaction

Tamiko Takahashi Faculty of Pharmaceutical Sciences, Toyama Medical & Pharmaceutical University, 2630 Sugitani, Toyama, 930-01, Japan
,
Noriyuki Kurose Faculty of Pharmaceutical Sciences, Toyama Medical & Pharmaceutical University, 2630 Sugitani, Toyama, 930-01, Japan
&
Toru Koizijmi Faculty of Pharmaceutical Sciences, Toyama Medical & Pharmaceutical University, 2630 Sugitani, Toyama, 930-01, Japan
Pages 367-368 | Published online: 23 Sep 2006
 
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Abstract

High diastereoselectivity of the endo cycloaddition of optically active α-alkoxycarbonyl thioaldehydes (2) with cyclopentadiene is achieved by a molecular designing of the compound (2).

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