Trithia[1.1.1]Propellane

Uri Zoller Haifa University, Oranim, Kiryat Tivon, 36910, Israel

Noel Riggs Australian National University, Canberra A.C.T., 2601, Australia

Minii Tho Nguyen Australian National University, Canberra A.C.T., 2601, Australia

Leo Radom Australian National University, Canberra A.C.T., 2601, Australia

Abstract

Trithia[1.1.1]propellane 2 is predicted to be a tightly-bound molecule which should be experimentally accessible. It is characterized by an intrabridgehead C-C bond of length 1.575Å, a heat of formation (ΔHℓ₂₉₈) of 542 kJ mol⁻¹, and vibrational spectra with frequencies all lying below 900 cm⁻¹. The synthesis of a key precursor to 2 is currently underway.

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Trithia[1.1.1]Propellane

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