Heterocyclic π-Donors, Macrocycles and Cage Molecules

Jan Becher Department of Chemistry, Odense University, DK-5230, Odense M, Denmark

Kim Christiansen Department of Chemistry, Odense University, DK-5230, Odense M, Denmark

Tine J⊘rgensen Department of Chemistry, Odense University, DK-5230, Odense M, Denmark

Thomas K. Hansen Department of Chemistry, Odense University, DK-5230, Odense M, Denmark

Abstract

π-Donors based on TIT-units have been intensively studied due to their potential use in conducting molecular materials. It therefore appeared of interest to use the readily avaible dithiolate (1) for the syntheses of macrocycles, exemplified by (3) and (4) and the lTF-cage molecules (5) - (7) obtained by intramolecular coupling^[1]:

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Heterocyclic π-Donors, Macrocycles and Cage Molecules

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Heterocyclic π-Donors, Macrocycles and Cage Molecules

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