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Original Articles

NOVEL REACTIONS OF SPIROSULFURANE PRECURSOR SULFIDES AND SULFOXIDES

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Pages 119-127 | Received 16 May 1993, Accepted 26 Oct 1993, Published online: 23 Sep 2006
 

Abstract

The SIV[C,C,N,O] spirosulfurane 19 and the lactam-sulfoxides 21, 22 and 23 with seven-, eight- and nine-membered rings have been prepared by oxidation and dehydration of trifluoroacetylaminoarylcarboxyphenyl sulfides and sulfoxides, respectively. A mechanism is proposed for the formations of lactam-sulfoxides. The preparation of the starting sulfides and sulfoxides is also described.

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