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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 90, 1994 - Issue 1-4
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Original Articles

Sulfenamides and Sulfinamides XI.†; Oxidation of Iodide Ion by an Aryl Sulfinamide

Kiyoko Fujiki School of Chemistry, The University of New South Wales, P.O. Box 1 Kensington N.S.W., 2033, Australia
,
Victor Clarke School of Chemistry, The University of New South Wales, P.O. Box 1 Kensington N.S.W., 2033, Australia
,
Edward R. Cole School of Chemistry, The University of New South Wales, P.O. Box 1 Kensington N.S.W., 2033, Australia
&
Peter T. Southwell-Keely School of Chemistry, The University of New South Wales, P.O. Box 1 Kensington N.S.W., 2033, Australia
Pages 79-84 | Received 26 May 1994, Published online: 23 Sep 2006
 
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Abstract

Oxidation of hydriodic acid by an aryl sulfinamide produced iodine in excess of the stoichiometric amount given by sulfoxides. The excess is explained by a secondary reaction with sulfenamide, the initial product, but is lessened by tertiary reactions including the formation of iodoaniline.

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