The Reaction Between Phenyliodonium Bis(Phenylsulfonyl)Methanide and Pyrrolidine

Spyros Nikas Laboratory of Organic Chemistry, University of Thessaloniki, Thessaloniki, 540-06, Greece

Nestor Rodios Laboratory of Organic Chemistry, University of Thessaloniki, Thessaloniki, 540-06, Greece

Aris Terzis Nuclear Research Center “Democritos” Aghia Paraskevi Attikis, Athens, Greece

Anastassios Varvoglis Laboratory of Organic Chemistry, University of Thessaloniki, Thessaloniki, 540-06, Greece; Prof. A. Varvoglis, Laboratory of Organic Chemistry, University of Thessaloniki, Thessaloniki, 540 06, Greece

Abstract

The main product from the title reaction is the enamine N-[2,2-bis(phenylsulfonyl)vinyl]-pyrrolidine, 4. Tetrakis(phenylsulfonyl)propane, 3, is a by-product, when dichloromethane is used; it is formed independently from this solvent and bis(phenylsulfonyl)methane in the presence of pyrrolidine.

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The Reaction Between Phenyliodonium Bis(Phenylsulfonyl)Methanide and Pyrrolidine

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