Abstract
Four new organosulphur phosphorus acid compounds have been obtained by sulphonation with liquid SO3: 2-fluorobenzylphosphonic and 4-fluorobenzylphosphonic acids gave 2-fluorobenzylphosphono-5-sulphonic and 4-fluorobenzylphosphono-3-sulphonic acids respectively, in nearly quantitative yields; 3-fluorobenzylphosphonic acid gave 3-fluorobenzylphosphono-6-sulphonic acid (85%) and 3-fluorobenzylphosphono-4-sulphonic acid (15%). Product structures are based on 13C magnetic resonance data. The entry of the SO3H group into the aromatic ring seems mainly ruled by the fluorine substituent.