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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 89, 1994 - Issue 1-4
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Original Articles

Synthesis of Dialkyl N-Alkyl-N-Perfluoroalkanesulfonyl Phosphoramidates

Shi-Zheng Zhu Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200032, China
,
Jie Zhang Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200032, China
,
Bin Xu Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200032, China
&
Aiwen Li Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200032, China
Pages 77-82 | Received 22 Jan 1994, Accepted 28 Mar 1994, Published online: 23 Sep 2006
 
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Abstract

N-Halogenperfluoroalkanesulfonylamines RfSO2N(R)X (X = Br, Cl) which are obtained by treatment of the sodium or potassium salt of N-alkylperfluoroalkanesulfonylamides RfSO2N(R)M with bromine or chlorine react readily with triethyl phosphite P(OEt)3 giving the title compounds RfSO2N(R)P(O)-(OEt)2. The reaction mechanism is discussed. Hydrolysis of these compounds gives the N—P bond broken products.

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