EXAMPLES OF 1,3,2-DIOXABENZO-PHOSPHOR(III)INANES

E. E. Nifantyev V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

T. S. Kukhareva V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

V. I. Dyachenko V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

A. O. Kolomietz V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

N. S. Magomedova V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

V. K. Belsky V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

L. K. Vasyanina V.I. Lenin Moscow State Pedagogical University, Department of Chemistry, Moscow, 119021, Russia

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Abstract

The concept allowing to synthesize hitherto unknown 1,3,2-dioxabenzo-phosphor(III)inanes is introduced. On the basis of ¹H, ¹⁹F, and ³¹P NMR evidence it was shown that the nature of the exocyclic substituent at the phosphorus atom can have a significant influence on the conformational features of the bicyclic phosphorinane ring system as well as on the chemical properties of this system. The study of the reactions between 2-dialkylaminobenzo-1,3,2-dioxaphosphor(III)inanes and proton containing nucleophiles confirmed the structures of the obtained compounds and exhibited their synthetic value.

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EXAMPLES OF 1,3,2-DIOXABENZO-PHOSPHOR(III)INANES

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EXAMPLES OF 1,3,2-DIOXABENZO-PHOSPHOR(III)INANES

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