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From the reaction of TAS-fluoride (Me2N)3S+Me3SiF2
−(1) and fluorotriazines (FCN)n(FSN)3−n (n = 1−3) and sulfanuric fluoride (FS(O)N)3 stable salts with the anions [(F2CN)(FCN)n-1(FSN)3-n]− and [(NS(O)F)3F]− are isolated. Interaction with P3N3F6 gives (TAS+)2 P3N3F5NPF2NPF2NPF5
2-, a cyclic-acyclic dianion. From the addition of F− to cyclic bis(imino)fluorosulfinate is formed, from S4N4 and 1 TAS+ S3N3
− is obtained.
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