REACTIVITY OF THE ACIDS OF TRIVALENT PHOSPHORUS AND THEIR DERIVATIVES. PART I. REDUCTIVE DEBROMINATION IN THE REACTIONS OF THE >P[sbnd]O⁻ IONS WITH 2-BROMOESTERS

Leszek Dembkowski Department of Organic Chemistry, Technical University of Gdańsk, ul. Narutowicza 11112, 80-952, Gdańsk, Poland

Janusz Rachon Department of Organic Chemistry, Technical University of Gdańsk, ul. Narutowicza 11112, 80-952, Gdańsk, Poland

Abstract

The reaction of α-bromocarboxylates with sodium dialkyl (diaryl) phosphites as well as sodium salt of dibenzylphosphine oxide in THF and alcohols as the solvents is described. Debromination of the starting materials occurs. Probable mechanisms namely SET and X-philic substitution are discussed.

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REACTIVITY OF THE ACIDS OF TRIVALENT PHOSPHORUS AND THEIR DERIVATIVES. PART I. REDUCTIVE DEBROMINATION IN THE REACTIONS OF THE >P[sbnd]O⁻ IONS WITH 2-BROMOESTERS

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REACTIVITY OF THE ACIDS OF TRIVALENT PHOSPHORUS AND THEIR DERIVATIVES. PART I. REDUCTIVE DEBROMINATION IN THE REACTIONS OF THE >P[sbnd]O− IONS WITH 2-BROMOESTERS

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REACTIVITY OF THE ACIDS OF TRIVALENT PHOSPHORUS AND THEIR DERIVATIVES. PART I. REDUCTIVE DEBROMINATION IN THE REACTIONS OF THE >P[sbnd]O⁻ IONS WITH 2-BROMOESTERS