N-PHOSPHANYLATED 1.3.2-OXAZA- AND 1.3.2-DIAZAPHOSPHOLANES AND -PHOSPHORINANES

Cornelia Mundt Institut für Anorganische and Allgemeine Chemie, Fachbereich Chemie der Humboldt–Universiät zu Berlin, Hessische Str. 1/2, 10115, Berlin, Germany

Lothar Riesel Institut für Anorganische and Allgemeine Chemie, Fachbereich Chemie der Humboldt–Universiät zu Berlin, Hessische Str. 1/2, 10115, Berlin, Germany

Abstract

The formation of the N-phosphanyl derivatives of the oxaza- and diazaphosphorinanes and -phospholanes 2-10 by the reaction of PX₃ (X = Cl, Br) with alcoholamines and diamines is described. The unusually large ² J _PNP coupling constants of the products are discussed.

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N-PHOSPHANYLATED 1.3.2-OXAZA- AND 1.3.2-DIAZAPHOSPHOLANES AND -PHOSPHORINANES

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N-PHOSPHANYLATED 1.3.2-OXAZA- AND 1.3.2-DIAZAPHOSPHOLANES AND -PHOSPHORINANES

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