ALKALINE C[sbnd]S BOND CLEAVAGE OF SOME ARYLTHIOMETHYL BENZOATES

Fatma El-Zahraa M. El-Hegazy Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt

Ali A. El-bardan Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt

Ezzat A. Hamed Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt

Abstract

Methyl and ethyl-[(substituted phenylthio)methyl]-3-nitrobenzoates and the corresponding non-nitro derivatives have been synthesized and their structures proven. The action of 5% sodium hydroxide solution on these esters gave the corresponding diaryl disulfides besides 3-nitro-4-methylbenzoic acid or 4-methylbenzoic acid.

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ALKALINE C[sbnd]S BOND CLEAVAGE OF SOME ARYLTHIOMETHYL BENZOATES

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ALKALINE C[sbnd]S BOND CLEAVAGE OF SOME ARYLTHIOMETHYL BENZOATES

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