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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 87, 1994 - Issue 1-4
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Original Articles

The Magic Salt Effects of Sodium Hexafluorophosphate

Didier Astruc Laboratoire de Chimie Organique et Organometallique, URA CNRS 35, Université Bordeaux I, 351, Cours de la Libération, 33405, TALENCE Cedex, FRANCE
,
Marie-hélène Laboratoire de Chimie Organique et Organometallique, URA CNRS 35, Université Bordeaux I, 351, Cours de la Libération, 33405, TALENCE Cedex, FRANCE
,
Delville-desbois Laboratoire de Chimie Organique et Organometallique, URA CNRS 35, Université Bordeaux I, 351, Cours de la Libération, 33405, TALENCE Cedex, FRANCE
,
Marc Lacoste Laboratoire de Chimie Organique et Organometallique, URA CNRS 35, Université Bordeaux I, 351, Cours de la Libération, 33405, TALENCE Cedex, FRANCE
,
Jaime Ruiz Laboratoire de Chimie Organique et Organometallique, URA CNRS 35, Université Bordeaux I, 351, Cours de la Libération, 33405, TALENCE Cedex, FRANCE
,
Françoise Moulines Laboratoire de Chimie Organique et Organometallique, URA CNRS 35, Université Bordeaux I, 351, Cours de la Libération, 33405, TALENCE Cedex, FRANCE
&
Jean-René Hamon Laboratoire de Chimie Organométallique, URA CNRS 415, Université Rennes I, Avenue du Général Leclerc, 35042, RENNES Cedex, FRANCE
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Pages 11-22 | Published online: 16 Feb 2007
 
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Abstract

The Na+PF6− salt changes the course of reactions between neutral or ionic substrates. Examples of reactions include superoxide radical chemistry, disproportionation, and C[sbnd]H and C[sbnd]O bond activation. This special salt effect is usually quantitative and sometimes catalytic. When compared to other salts, Na+PF6− by far gives the most spectacular results, due to the small size of Na+ as compared to large organometallic cations.

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