SYNTHESIS OF PENTADIENYLIUM IONS WITH N-SILYLATED PHOSPHAIMINES, CHARACTERIZATION AND REACTIVITY

M. P. Fialon Laboratoire de Synthese et Physicochimie Organique Associé au CNRS, Universite Paul Sabatier, 118 Route de Narbonne, F-31062, Toulouse Cedex

M. R. Maziéres Laboratoire de Synthese et Physicochimie Organique Associé au CNRS, Universite Paul Sabatier, 118 Route de Narbonne, F-31062, Toulouse Cedex

Y. Madaule Laboratoire de Synthese et Physicochimie Organique Associé au CNRS, Universite Paul Sabatier, 118 Route de Narbonne, F-31062, Toulouse Cedex

C. Payrastre Laboratoire de Synthese et Physicochimie Organique Associé au CNRS, Universite Paul Sabatier, 118 Route de Narbonne, F-31062, Toulouse Cedex

M. Sanchez Laboratoire de Synthese et Physicochimie Organique Associé au CNRS, Universite Paul Sabatier, 118 Route de Narbonne, F-31062, Toulouse Cedex

J. G. Wolf Laboratoire de Synthese et Physicochimie Organique Associé au CNRS, Universite Paul Sabatier, 118 Route de Narbonne, F-31062, Toulouse Cedex

A. O. Gudima Institute of Organic Chemistry, Ukrainian Academy of Sciences, Murmanskaya st 5, 25 3660, Kiev 94, Ukraine

V. D. Romanenko Institute of Organic Chemistry, Ukrainian Academy of Sciences, Murmanskaya st 5, 25 3660, Kiev 94, Ukraine

show all

Abstract

By condensation of a carboxonium salt with N-silylated phosphaimines new types of pentadienylium salts are obtained. These new compounds are characterized by NMR spectroscopy, UV and mass spectra. Their aza-Wittig reactivity towards isocyanides is described.

Key Words:

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

SYNTHESIS OF PENTADIENYLIUM IONS WITH N-SILYLATED PHOSPHAIMINES, CHARACTERIZATION AND REACTIVITY

Information for

Open access

Opportunities

Help and information

SYNTHESIS OF PENTADIENYLIUM IONS WITH N-SILYLATED PHOSPHAIMINES, CHARACTERIZATION AND REACTIVITY

Abstract

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature