Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 108, 1996 - Issue 1-4
Submit an article Journal homepage
71
Views
8
CrossRef citations to date
0
Altmetric
Original Articles

REACTION OF ACYL ISOTHIOCYANATES WITH NUCLEOPHILES: A CONVENIENT SYNTHESIS OF 1,3-OXAZINE, PYRIMIDINETHIONE AND THIAZOLE DERIVATIVES

M. G. Assy Chemistry Department, Faculty of Science, Zagazig University, Zagazig, Egypt
Pages 15-20 | Received 24 May 1995, Accepted 22 Jul 1995, Published online: 24 Sep 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The reaction of acetyl isothiocyanate 1 with ethyl cyanoacetate, malononitrile and/or a cyclic β-diketone afforded the corresponding 1,3-oxazines 3, 11 and thioamide 12 respectively. The heteroannulation of 3 and the synthesis of thiazole 18 is described.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Synthesis of novel 10-Se-3 type selenatetraazapentalene derivatives with a hypervalent selenium.
Source: The Chemical Society of Japan
Filter Paper Disc Modification of the Oxford Cup Penicillin Determination.
Source: SAGE Publications
Isothiocyanates in the chemistry of heterocycles
Source: American Chemical Society (ACS)
A CONVENIENT SYNTHESIS OF FUSED 4-MERCAPTOPYRIMIDINES FROM o-AMINONITRILES
Source: American Chemical Society (ACS)
Reaction of oxalyl chloride and alkyloxalyl chlorides with isocyanates and isothiocyanates
Source: American Chemical Society (ACS)
Synthesis of heterocyclic compounds. XXXIX. Synthesis of 5‐cyano‐2‐phenyl‐4‐thioxo‐3,4‐dihydropyrimidines
Source: Wiley
Novel heteropentalenes. Synthesis of heteropentalenes from tetrahydroimidazo [1.2-d]-(1,2,4)-thiadiazoles and conversion of certain heteropentalenes to benzothiazole derivatives
Source: Elsevier BV
Design and chemical behavior of novel pyrimidine derivatives and their evaluation of cytotoxicity
Source: Taylor & Francis
Heterocyclic syntheses with malonyl chloride. 15. 7-Chloro-3,4-dihydro-4,5-dioxo-3-aryl(or-alkyl)-2-thio-2H,5H-pyrano[3,4-2-e]-1,3-oxazine from aryl or alkyl isothio-cyanates and their degradation with morpholine and ethanol
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.