Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 108, 1996 - Issue 1-4
Submit an article Journal homepage
68
Views
25
CrossRef citations to date
0
Altmetric
Original Articles

HETEROCYCLEN ALS LIGANDEN XXII. 2-CHALKOGENOIMIDAZOLINE ALS LIGANDEN IN PENTACARBONYLMETALL-KOMPLEXEN

Norbert Kuhn Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-72076, Tübingen, Deutschland
,
Riad Fawzi Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-72076, Tübingen, Deutschland
,
Thomas Kratz Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-72076, Tübingen, Deutschland
,
Manfred Steimann Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-72076, Tübingen, Deutschland
&
Gerald Henkel Fachbereich 6 (Chemie) der Universität-Gesamthochschule Duisburg, Lotharstraße 1, D-47048, Duisburg, Deutschland
Pages 107-119 | Received 27 Jul 1995, Accepted 05 Sep 1995, Published online: 24 Sep 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The chalcogenoimidazoline complexes N—CMe—CMe—NR—C=X·M(CO)3 (VIII-XI; R = Me, iso-Pr; X = S, Se, Te; M = Cr, Mo, W) are obtained from the metal hexacarbonyls (M = Cr, Mo, W) and the chalcogenoimidazolines IV-VII. In these complexes the chalcogeno ligands exhibit strong donor properties according to the sequence Te > Se > S which is demonstrated by n. m. r. and i. r. data. The X-ray structures of N(iso-Pr)—CMe—CMe—N(iso-Pr)—C=X·Cr(CO)3 (X = S; Se; VIIIa, IXa) are reported.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Heterozyklen als liganden: XX. Spektroskopische und strukturelle charakterisierung von pentacarbonylmetall-komplexen der imidazol-2-ylidene☆
Source: Elsevier BV
Transition metal mediated formation of dicationic diselenides stabilised by N-heterocyclic carbenes: designed synthesis
Source: Royal Society of Chemistry (RSC)
Die Bindungsverhältnisse in Phosphantelluriden. Eine empirische NMR-Studie und die Kristallstruktur von (iso-C3H7)3PTe [1] / The Nature of the Bonding in Phosphane Tellurides. An Empirical NMR Study and the Crystal Structure of (iso-C3H7)3PTe [1]
Source: Walter de Gruyter GmbH
26.1 - Chromium Compounds with η 1 -Carbon Ligands
Source: Elsevier
METALLORGANISCHE VERBINDUNGEN DER LANTHANOIDE. XCVI: YLIDARTIGE OLEFINKOORDINATION IN KOMPLEXEN DREIWERTIGER 4F-ELEMENTE
Source: Elsevier BV
Synthesis of Imidazol-2-ylidenes by Reduction of Imidazole-2(3H)-thiones
Source: Georg Thieme Verlag KG
2-Selenoimidazoline / 2-Selenoimidazolines
Source: Walter de Gruyter GmbH
Carbon compounds of the transition metals. Part XXIV. The crystal and molecular structure of pentacarbonyl[methyl(phenylthio)carbene]-chromium
Source: Royal Society of Chemistry (RSC)
M(CO)5(R3PTe)(M = Cr, Mo, W; R = But): the first stable tellurophosphorane complexes
Source: Royal Society of Chemistry (RSC)
Novel Zwitterionic Sulfides, Selenides and Tellurides
Source: Wiley
Crystal and molecular structure of Cr(CO)5(SCMe2), a thioketone complex
Source: Elsevier BV
Isolation of chromium(0) thiols: molecular structure of (tert-butylmercaptan)pentacarbonylchromium
Source: American Chemical Society (ACS)
Crystal and molecular structure of pentacarbonyl(trimethylphosphine sulphide)chromium(0)
Source: Royal Society of Chemistry (RSC)
Thioketone complexes of chromium, molybdenum, and tungsten carbonyls
Source: Elsevier BV
Beiträge zur Chemie des Imidazols. III: 2-Telluroimidazoline : stabile Tellurocarbonyl-Verbindungen
Source: Wiley
Synthesis, characterization, and X-ray crystallographic structure of 1,3-dimethyl-2(3H)-imidazoleselone
Source: Wiley
Kristall- und molekülstruktur von pentacarbonyltetrahydrofuran-chrom(0)
Source: Elsevier BV
Derivate des Imidazols, XI. (C8H14N2)M(CO)5 (M = Mo, W) ‐ Terminale Koordination eines Olefins in Pentacarbonylmetall‐Komplexen
Source: Wiley
Darstellung und Charakterisierung von Spezies der Zusammensetzung η5-C5H5Cr(NO)2SR (R = C6H5, C6F5, t–C4H9) und [η5-C5H5CrNO]2(ER)2 (E = O, S, Se, Te, R = Alkyl, Aryl); Röntgenstrukturanalysen von [η5-C5H5(NO)Cr(μ-SeC6H5)2Cr(NO)-η5-C5H5] und [η5-C5H5(NO)Cr(μ-Se-n-C4H9)(μ-OH)Cr(NO)-η5-C5H5] / Synthesis and Characterization of Species of Composition η5-C5H5Cr(NO)2SR (R = C6H5, C6F5, t-C4H9) and [η5-C5H5CrNO]2(ER)2 (E = O, S, Se, Te, R = Alkyl, Aryl); Röntgenstrukturanalysen von [η5-C5H5(NO)Cr(μ-SeC6H5)2Cr(NO)-η5-C5H5] and [η5-C5H5(NO)Cr(μ-Se-n-C4H9)(μ-OH)Cr(NO)-η5-C5H5]
Source: Walter de Gruyter GmbH
Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen: CXXVI. Heterocyclen-Carbene als phosphananaloge Liganden in Metallkomplexen
Source: Elsevier BV
The molecular structure of 1,3-dimethyl-2(3H)-imidazolethione (C5H8N2S)
Source: Royal Society of Chemistry (RSC)
Redox Reaction between Main-Group Elements (Te, Sn, Bi) and N-Heterocyclic-Carbene-Derived Selenium Halides: A Facile Method for the Preparation of Monomeric Halides
Source: Wiley
Studies of tellurium shielding by heteronuclear magnetic double resonance in a representative series of compounds
Source: Royal Society of Chemistry (RSC)
Syntheses and Structures of Molybdenum, Tungsten, and Manganese Complexes of a Cyclic Thiourea, [M(CO)5(SC3N2Me4)] (M = Mo, W) and [{CpMn(CO)2}2(μ‐SC3N2Me4)]
Source: Wiley
[pi]-acidity of thioethers and selenoethers: Truth or fiction A comparative density functional study
Source: American Chemical Society (ACS)
1,3,4,5-Tetramethyl-2-methyleneimidazoline—an ylidic olefin
Source: Royal Society of Chemistry (RSC)
Crystal structure and mass spectrometry of dibromodimethyl[1-methyl-2(3H)-imidazolinethione-S]tin(IV)
Source: Royal Society of Chemistry (RSC)
Crystal and molecular structures of bis[(.eta.5-cyclopentadienyl)dicarbonylchromium]sulfide, a novel organometallic complex possessing a chromium.tplbond.sulfur.tplbond.chromium linkage
Source: American Chemical Society (ACS)
Cyclopentadienyleisen-komplexe mit ER2-ligangen (E = S, Se, Te); Synthese und spektroskopische charakterisierung
Source: Elsevier BV
Dichloridobis(1,3-diisopropyl-4,5-di-methyl-1H-imidazol-3-ium-2-thiol-ate-κS)copper(II).
Source: (:unav)
Telluroureas and derived transition metal complexes: the crystal and molecular structure of [Cr(CO)5{TeCN(Et)CH2CH2NEt}]
Source: Royal Society of Chemistry (RSC)
Complexes of molybdenum hexacarbonyl with imadazolethione molecules
Source: Elsevier BV
Chemische und spektroskopische untersuschungen an komplex-kationen des types [C5H5Fe(CO)2(R3EX)]+. Ein beitrag zur diskussion der koordinationseigenschaften von phosphanchalkogeniden und deren höheren homologen
Source: Elsevier BV
CCDC 107132: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
N‐Heterocyclische Carbene
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.