PREPARATION OF 3-LONG-CHAIN SUBSTITUTED 5-MEMBERED HETEROARYLENES AND STUDIES OF THEIR LANGMUIR-BLODGETT FILM FORMATION

Cynthia A. F. Striley University of Cincinnati, Department of Chemistry, Cincinnati, Ohio, 45221-0172, USA

Adel Amer University of Cincinnati, Department of Chemistry, Cincinnati, Ohio, 45221-0172, USA; Department of Chemistry, Faculty of Science, United Arab Emirates University, P.O. Box 17551, Al Ain, U.A.E.

Wei Yuan Zhang University of Cincinnati, Department of Chemistry, Cincinnati, Ohio, 45221-0172, USA

Hans Zimmer University of Cincinnati, Department of Chemistry, Cincinnati, Ohio, 45221-0172, USA

Jerome B. Lando Case Western Reserve University, Department of Macromolecular Science, Cleveland, Ohio, 44106, USA

Abstract

The synthesis of amphiphilic thiophene 1 and pyrrole 5 were achieved via Wittig and Friedel-Crafts reactions respectively. The ability of 1 and 5, as well as 3-heptadecylthiophene and poly(3-heptadecylthiophene), to form Langmuir-Blodgett films are discussed.

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PREPARATION OF 3-LONG-CHAIN SUBSTITUTED 5-MEMBERED HETEROARYLENES AND STUDIES OF THEIR LANGMUIR-BLODGETT FILM FORMATION

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PREPARATION OF 3-LONG-CHAIN SUBSTITUTED 5-MEMBERED HETEROARYLENES AND STUDIES OF THEIR LANGMUIR-BLODGETT FILM FORMATION

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