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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 115, 1996 - Issue 1
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Original Articles

UNEXPECTED FORMATION AND MOLECULAR STRUCTURE OF 2,2,6,6-TETRA-t-BUTYL-4,8-DIMETHYL-1,5,9-TRIOXA-4,8-DISILA-2,6-DISTANNABICYCLO[3.3.1]NONANE

Klaus Jurkschat Fachbereich Chemie der Universität Dortmund, Lehrstuhl für Anorganische Chemie II, D-4421, Dortmund, Germany
,
Fred Rosche Fachbereich Chemie der Universität Dortmund, Lehrstuhl für Anorganische Chemie II, D-4421, Dortmund, Germany
&
Markus Schurmann Fachbereich Chemie der Universität Dortmund, Lehrstuhl für Anorganische Chemie II, D-4421, Dortmund, Germany
Pages 161-167 | Received 11 Jan 1996, Accepted 05 Mar 1996, Published online: 24 Sep 2006
 
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Abstract

The title compound 2 has been prepared by treatment of (i-PrO)2MeSiCH2(t-Bu)2SnCl 1 with potassium fluoride/water. Multinuclear NMR and X-ray studies reveal 2 adopts bicyclo[3.3.1]nonane structure. 2 crystallizes in the monoclinic space group P2(1)/n with unit cell dimensions a = 12.880(3), b = 16.949(4), c = 13.472(4) Å, β 93.04(2)°, Z = 4. The structure was refined to a final R value of 0.065.

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