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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 115, 1996 - Issue 1
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Original Articles

REACTION OF 3,3 DIMETHYL-1-PHOSPHABUTYNE, tBuCP, WITH TRIRUTHENIUM DODECACARBONYL AND TRIOSMIUM DODECACARBONYL

Rainer Bartsch Institut für Anorganische and Analytische Chemie der Technischen Universität, Postfach 3329, D-38023, Braunschweig, Germany
,
Alexander J. Blake Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom
,
Brian F. G. Johnson Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom
,
Peter G. Jones Institut für Anorganische and Analytische Chemie der Technischen Universität, Postfach 3329, D-38023, Braunschweig, Germany
,
Christian Müller Institut für Anorganische and Analytische Chemie der Technischen Universität, Postfach 3329, D-38023, Braunschweig, Germany
,
John F. Nixon School of Chemistry and Molecular Sciences, University of Sussex, Brighton, BN1 9QJ, United Kingdom
,
Mathias Nowotny Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom
,
Reinhard Schmutzler Institut für Anorganische and Analytische Chemie der Technischen Universität, Postfach 3329, D-38023, Braunschweig, Germany
&
Douglas S. Shephard Institut für Anorganische and Analytische Chemie der Technischen Universität, Postfach 3329, D-38023, Braunschweig, Germany
 show all
Pages 201-215 | Received 13 Mar 1996, Accepted 14 Mar 1996, Published online: 24 Sep 2006
 
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Abstract

Reaction of 1Bu[sbnd]C[tbnd]P with [Ru3(CO)12] or [Os3(CO)12] afforded the novel phosphinidene complexes [Ru3(CO)9(PC(CO)1Bu}2] 1 or [Os1(CO)9(PC(CO)1Bu}2] 2, respectively. A crystal structure analysis revealed a nido structure for both complexes in agreement with a contribution of four electrons to the cluster framework by each phosphinidene ligand. A minor product of the reaction with [Os3(CO)12] is the complex [Os3(CO)9(P(C(CO)1Bu)C(1Bu)P(Os3(CO)11))] 3, consisting of two triosmium units linked by a P[sbnd]C[sbnd]P framework resulting from coupling of phosphinidene and phospha-alkyne fragments. Complex 3 was also characterized by means of a crystal structure analysis.

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Related Research Data

Mode of attachment of the triply-bridging C6H4 ligand in open triosmium clusters: Crystal structures and fluxionality of the clusters [Os3(PMe)(C6H4)(CO)8L] (L = CO or PEt3)
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Remarkable carbonylation of a co-ordinated phospha-alkyne ButCP to afford the novel phosphinidene ligand ButC(CO)P, crystal and molecular structure of [Re2(CO)8Pt(dppe){ButC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane)
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