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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 115, 1996 - Issue 1
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Original Articles

MONO- AND DIALKYLATION OF ISOPROPYL PHOSPHINATE-A SIMPLE PREPARATION OF ALKYLPHOSPHINATE ESTERS1

Michael J. Gallagher School of Chemistry, University of New South Wales, Sydney, NSW, 2052, Australia
,
Millagahamada G. Ranasinghe School of Chemistry, University of New South Wales, Sydney, NSW, 2052, Australia
&
Ian D. Jenkins Faculty of Science and Technology, Griffith University, Nathan, 4111, Queensland, Australia
Pages 255-259 | Received 25 Mar 1996, Accepted 29 Mar 1996, Published online: 24 Sep 2006
 
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Abstract

Base-catalysed alkylation of isopropyl phosphinate with primary alkyl halides under mild conditions affords the corresponding alkyl phosphinate esters in fair to excellent yields.

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