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Original Articles

SYNTHESES AND SPECTROSCOPIC STUDIES OF DIORGANOTIN BIS-O-ALKYL PHOSPHONATES

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Pages 179-183 | Received 10 Aug 1995, Accepted 11 Nov 1995, Published online: 04 Oct 2006
 

Abstract

Diorganotin bis-O-alkyl phosphonates, R2Sn[O2P(H)OR′]2 (R = Me, Et; R′ = Me, Et, Bu, Ph) have been obtained in quantitative yield by reacting sodium salts of O-alkyl phosphonate with diorganotin dichloride. The derivatives are white colored, hydrolytically stable powdery solids, soluble in methanol (when freshly prepared) and are characterized by various physico-chemical as well as spectroscopic IR, NMR (1H, 31P and 119Sn) studies which are consistent with 6-coordinated tin atom.

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