Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 113, 1996 - Issue 1-4
Submit an article Journal homepage
154
Views
8
CrossRef citations to date
0
Altmetric
Original Articles

REDISTRIBUTION OF DICHLOROSILANES AND DIHYDRIDOSILANES. SYNTHESIS OF CHLORO HYDRIDOSILANES

A. Benouargha Université Mohamed V, Laboratoire de Chimie Organique Hétérocyclique, Faculté des Sciences, Rabat, Morocco
,
D. Boulahia URA D 1193 CNRS, Laboratoire de Chimie Appliquée, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34053, Montpellier Cedex 1, France
,
B. Boutevin URA D 1193 CNRS, Laboratoire de Chimie Appliquée, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34053, Montpellier Cedex 1, France
,
G. Caporiccio Dow Corning Corp, Midland, Michigan, USA; Via E. Filiberto 13, Milano, Italy
,
F. Guida-pietrasanta URA D 1193 CNRS, Laboratoire de Chimie Appliquée, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34053, Montpellier Cedex 1, France
&
A. Ratsimihety URA D 1193 CNRS, Laboratoire de Chimie Appliquée, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34053, Montpellier Cedex 1, France
Pages 79-87 | Received 14 Nov 1995, Accepted 05 Dec 1995, Published online: 04 Oct 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The redistribution of dichlorosilanes RSi(CH3)Cl2 and dihydridosilanes RSi(CH3)H2, prepared by reduction of the homologues dichlorosilanes, in the presence of a quaternary ammonium salt is presented. The influence of the nature of R (fluoroalkyl chain RFCH2CH2 with RF = CF3, C4F17, alkyl chain R [dbnd] C6H13 or aromatic R [dbnd] C6H5) and of the temperature on the rate of the reaction is studied. The equilibrium constants and free enthalpies are calculated and discussed taking into account the nature of R. The new products described were characterized from I.R. 1H, 19F and 29Si NMR spectroscopies.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Neutral and Cationic Silicon Species Containing Aryl-OCO- or Aryl-SCS-Type Pincer Ligands: Synthesis, Structure, Bonding, and Comparison with Aryl-NCN Systems
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.