Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 113, 1996 - Issue 1-4
Submit an article Journal homepage
6
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

2,4-BIS(METHYLTHIO)-2,4-DITHIOXO-1,3,2,4- DIAZADIPHOSPHETIDINES-NMR CHARACTERIZATION AND CRYSTAL STRUCTURE

Gisela Ohms Institut für Analytische Chemie der Technischen Universität Dresden, Mommsenstraβe 13, D-01062, Dresden, Germany
,
Jörg Zessin Institut für Analytische Chemie der Technischen Universität Dresden, Mommsenstraβe 13, D-01062, Dresden, Germany
&
Zdirad Žák Department of Inorganic Chemistry, Mazaryk University Kotlárska 2, 61137, Brno, Czech Republic
Pages 107-121 | Received 05 Dec 1995, Published online: 04 Oct 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

New diazadiphosphetidines of the composition [MeSP(S)NR]2 have been investigated by 31P, 13C and 1H NMR spectroscopy and the configuration of the ring compound has been assigned. Structures of the 1,3-diphenyl compound 1g and the 1,3-di(ortho-tolyl) compound 1h have been determined by X-ray single-crystal analysis. Crystals of 1g and 1h grown from chloroform are colourless prisms of trans configuration. Single crystals of 1h obtained from dichloromethane are colourless plates of cis configuration. Crystal data: 1g (trans) monoclinic, C2/c, Z = 4, a = 9.373(2), b = 16.145(3), c = 11.705(2) Å, β = 92.11(3)°; 1h (trans) monoclinic, P21/n, Z = 2, a = 7.083(1), b = 18.275(4), c = 8.257(2) Å, β = 110.13(3)°; 1h (cis) monoclinic, P21/n, Z = 4, a = 9.994(2), b = 15.702(2), c = 13.668(5) Å, β = 105.14(2)°.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Synthese, Eigenschaften und NMR-spektroskopisch Untersuchung von Phenylthiophosphons�ure-bis(trimethylsilylamid) und 1,3-Bis(trimethylsilyl)-2,4-diphenyl-2, 4-dithioxo-1,3,2?5,4?5-diazadiphosphetidin
Source: Wiley
�ber die Bildung neuer Azathiadiphosphetidine
Source: Wiley
Structural characterization of trans-2,4-dithio-2,4-dianilino-1,3-diphenyl-1,3,2,4-diazadiphosphetidine, [(C6H5NH)P(S)NC6H5]2
Source: American Chemical Society (ACS)
Phosphorus–nitrogen compounds. Part 56. The solution synthesis of some trans-1,3-dialkyl-2,4-diphenyl-2,4-dithiocyclodi-λ5-phosphazanes and their proton, carbon-13, and phosphorus-31 nuclear magnetic resonance spectra
Source: Royal Society of Chemistry (RSC)
Preparation and Crystal Structure of New 1,3-Diaza-λ5,λ5-diphosphetidines
Source: Walter de Gruyter GmbH
The crystal and molecular structure of cis-1,3-diethyl-2,4-diphenyl-2,4-dithiocyclodiphosphazane
Source: International Union of Crystallography (IUCr)
Synthesis and Isolation ofcis- andtrans-1,3,2?3, 4?3-Diazadiphosphetidine
Source: Wiley
Synthesis and vibrational spectra of some 1,3-diaryl-2,4-diphenyl-2,4-dithiocyclodiphosphazanes, [PhP(S)NAr]2
Source: Elsevier BV
Synthese, Eigenschaften und NMR-spektroskopische Untersuchungen an 2,4-Dithioxo-2,4-dimercapto-1,3-diaza-2?5,4?5-diphosphetidinen
Source: Wiley
Two different modes of avoiding steric crowding in ortho-substituted N-phenlcyclodiphosph(V)azanes; X-ray crystal structures of two derivatives
Source: Royal Society of Chemistry (RSC)
Cis/Trans Isomerization and Conformational Properties of 2,4-Bis(primary amino)-1,3,2,4-Diazadiphosphetidines
Source: American Chemical Society (ACS)
Neue 1,3,2,4-Diazadiphosphetidine
Source: Wiley
CCDC 106022: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Cis-trans-Isomere von Diazadiphosphetidin-Derivaten: Fünf Kristall- und Molekülstrukturen / Cis-trans Isomers of Diazadiphosphetidine Derivatives: Five Crystal and Molecular Structures
Source: Walter de Gruyter GmbH
PHOSPHAZENES AND PHOSPHAZANES
Source: Informa UK Limited
�ber Thiophosphors�ure-pyrididiumbetaine
Source: Wiley
ÜBER DIAZADIPHOSPHETIDINE. V1 SYNTHESE UND STRUKTUR VON 1.3.2.4-DIAZA-Λ5,Λ3-UND Λ5,Λ5-DIPHOSPHETIDINEN
Source: Informa UK Limited
1,3-Di-tert-butyl-2,4-bis(dimethylamino)-2,4-dithio-cyclo-di(phosphazane)
Source: International Union of Crystallography (IUCr)
COMMENTS ON N.M.R. SPECTRA OF THE XnAA′Xn′ TYPE
Source: Canadian Science Publishing
New Diaza- and Thiazadiphosphetidines from the Dithiophosphoric Acid Chloride Betaine and Primary Amines via Monometaphosphate Analogous Intermediates
Source: Informa UK Limited
Crystal structure of 1,3-diisopropyl-2,4-diisopropylamino-2,4-dithioxo-1,3,2-λ5,4λ5-diazadiphosphetidine, C12H28N4P2S2
Source: Walter de Gruyter GmbH
CCDC 106020: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
CCDC 106021: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
THE STRUCTURES AND MODE OF FORMATION OF SOME CYCLODIPHOSPH(V)AZANES AND THEIRCIS-TRANSISOMERISATION
Source: Informa UK Limited

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.