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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 111, 1996 - Issue 1-4
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Original Articles

Zirconium Promoted Ring Opening. A New Route to Phosphinites and Polyphosphinites

Nathalie Ccnac Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077, Toulouse Cedex, France
,
Maria Zablocka Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza, 11290-362, Lodz, Poland
,
Main Igau Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077, Toulouse Cedex, France
,
Jean-Pierre Maioral Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077, Toulouse Cedex, France
&
Aleksandra Skowronska Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza, 11290-362, Lodz, Poland
Page 59 | Published online: 23 Oct 2006
 
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Abstract

Ring opening reactions involving various heterocycles, the Schwartz reagent [Cp2ZrHC1]n and a number of chlorophosphines or phosphenium salts will be presented. Scope and limitations of this useful methodology will be discussed.

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