Influence of an Organophosphorus Substituent on the Neighboring Reaction Center

Abstract

α-Functionalized organophosphorus substances containing P(O)-C-X fragment (where X is a functional group) are not only extremely promising syntones for the synthesis of various types of organophosphorus structures, but present a very convenient objects for the quantitative studies of electronic and steric influence of a complex organophosphorus group on the reactivity of various reaction centers.