Hydride Transfer Reactions of Aminomethylphosphines and Bis(Amino)Methanes with Diphenylboric Acid Ester in the Presence of Carbonyl Compounds

E. R. Mustakimov A.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Kazan, Russia

A. S. Balueva A.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Kazan, Russia

G. N. Nikonov A.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Kazan, Russia

Abstract

The interaction of diethylaminomethylphosphines and diphenylboric acid isobutyl ester proceeds only in the presence of active carbonyl compounds, namely alkyl aldehydes, followed by the formation of 1,3,2,5-dioxaborataphosphoniarinanes with the second molecule of the carbonyl compound. Reactions don't take place in the presence of ketones and aromatic aldehydes. Bis(N,N-diethylamino)methane reacts analogously to give corresponding N,B-containing zwitter-iones.

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Hydride Transfer Reactions of Aminomethylphosphines and Bis(Amino)Methanes with Diphenylboric Acid Ester in the Presence of Carbonyl Compounds

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Hydride Transfer Reactions of Aminomethylphosphines and Bis(Amino)Methanes with Diphenylboric Acid Ester in the Presence of Carbonyl Compounds

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