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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 111, 1996 - Issue 1-4
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Original Articles

C-Spirooxyphosphoranyl (Pv) α-Anions. Alkylation and Olefination Chemistry

Salim Barkallah The William Rand Kenan Jr., Laboratories of Chemistry, The University of North Carolina, Chapel Hill, NC, 27599-3290, USA
,
Mihaela L. Bojin The William Rand Kenan Jr., Laboratories of Chemistry, The University of North Carolina, Chapel Hill, NC, 27599-3290, USA
&
Slayton A. Evans Jr. The William Rand Kenan Jr., Laboratories of Chemistry, The University of North Carolina, Chapel Hill, NC, 27599-3290, USA
Page 156 | Published online: 23 Oct 2006
 
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Abstract

The chemical features of C-spirooxyphosphoranyl α-anions are investigated toward alkylation and olefination reactions. Proposed mechanistic pathways are based on low temperature 31P-NMR data.

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