TETRAPHENYL PHOSPHONIUM AND ARSONIUM SALTS OF ALKYLENE DITHIOPHOSPHATO MOIETIES

Abstract

Complexes of the type [Ph₄M]⁺[S₂POGO]⁻ (M[dbnd]Por As; G= -CMe₂CH₂CHMe-, CH₂CMe₂CH_2⁻ , -CH₂CEt₂CH_2⁻ , -CMe₂CMe_2⁻ and -CH₂CH₂CHMe-) have been synthesized by the reactions of tetraphenyl phosphonium and arsonium chloride with ammonium alkylene dithiophosphates. The derivatives have been chracterized by elemental analyses, molar conductance spectroscopic (IR, ¹H and ³¹P NMR) studies.

Key Words:

• Tetraphenylphosphonium chloride
• tetraphenylarsonium-chloride
• alkylenedithiophosphates
• molar conductance