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Original Articles

REACTION OF N-(N′,N′,N″,N″-TETRAMETHYL)GUANIDINE- SUBSTITUTED PHOSPHINES WITH ANTIMONY PENTACHLORIDE AND WITH BORON TRIFLUORIDE

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Pages 171-176 | Received 13 Jan 1997, Accepted 28 Jan 1997, Published online: 04 Oct 2006
 

Abstract

The N-(N′,N′,N″,N″-tetramethyl)guanidinyl substituted phosphines 1, boron trifluoride and antimony pentachloride. Instead of the expected Lewis acid-base adducts the phosphonium compounds 3-5, followed by the formation of the σ34 P+-phosphonium compound 3, leading to the chlorophosphonium hexachloroantimonates 4, and 5.

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